Product ID:POLYSEAMSEAL ADHESIVE CAULK
MSDS Date:09/21/1987
FSC:8030
NIIN:00N023820
MSDS Number: BLYQL

DARWORTH CO

TOWER LANE
AVON, CT 06001
US

Emergency Phone: 203-677-7721; 800-624-7767

Info Phone: 800-672-3499; 800-228-7103

Preparer: M HAWKES

Cage: IO148

DARWORTH INC

K AVON, CT 06001 US

Telephone: 203-677-7721

Cage: 51405

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1-5%

OSHA PEL 150 PPM;200 STEL

ACGIH TLV: 150 PPM;200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PHTHALIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE)

CAS: 84-74-2

RTECS: TI0875000

Fraction By Weight: 5-10%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYLENE GLYCOL

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 2%

OSHA PEL 50 PPM,C

ACGIH TLV: 50 PPM,C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

VENTILATION PROVES INADEQUATE TO MAINTAIN SAFE VAPOR

RTECS: 9999999ZZ

IN ANIMALS (DBP). LIVER DAMAGE, NAUSEA AND

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY BE AN IRRITANT. SKIN:MAY CAUSE
IRRITATION UPON PROLONGED OR REPEATED CONTACT. INHAL:ETHYLENE
GLYCOL IS VERY TOXIC IN PARTICULATE FORM UPON INHALATION. HIGH
CONCENTRATIONS OF BUTYL ACETATE ARE IRRITANT OF RESPIRATORY TRACT
& CAUSE NARCOSIS. INGEST:LETHAL DOSE OF ETHYLENE GLYCOL FOR MAN
REPORTED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:TO BE 100ML. IF INGESTED, ETHYLENE
GLYCOL CAUSES INITIAL CNS STIMULATION FOLLOWED BY DEPRESS. LATER,
IT CAUSES KIDNEY DMG WHICH CAN TERMINATE FATALLY. VARIOUS STUDIES
HAVE SHOWN A POSS ASSOC W/EXPOS TO DIBUTYL PHTHALATE (DBP) &
ETHYLENE GLYCOL (EG) & FOLLOWING SYS EFTS. RESP TRACT IRRIT, KIDNEY
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS.
GET MD IMMED. SKIN:WASH WITH SOAP & LARGE QUANTITYS OF WATER & GET
MD IF IRRIT PERSISTS. INHAL:IF BRTHG DFCLTIES, DIZZINESS, OR LIGHT
HEADED NESS OCCUR WHEN WORKING IN AREAS W/HIGHVAPOR CONCECTRATIONS,
REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE ARTF RESP & GET MD
IMMEDIATELY. INGEST:INDUCE VOMITING IS CONSCIOUS. GET MD
IMMEDIATELY.

Extinguishing Media:WATER, FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOHS/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER MAY BE UNSUITABLE AS EXTING MEDIUM, BUT HELPFUL IN KEEPING
ADJACENT CNTNRS COOL. AVOID (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP WORK AREAS FREE OF HOT METAL
SURFACES AND OTHER SOURCES OF IGNITION.

Spill Release Procedures:KEEP SOURCES OF IGNITION AND HOT METAL
SURFACES ISOLATED FROM SPILL. SPILLED MATERIAL MAY BE REMOVED WITH
INERT ABSORBANT AND SHOVEL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP PRODUCT CONTAINERS COOL, DRY &
AWAY FROM SOURCES OF IGNIT. USE & STORE W/ADEQ VENT. KEEP
CONTAINERS CLOSED WHEN NOT IN USE. KEEP FROM FREEZING.
Other Precautions:AVOID INHALATION OF VAPORS. PERSONAL CONTACT WITH THE
PRODUCT SHOULD BE AVOIDED. SHOULD CONTACT BE MADE, REMOVE SATURATED
CLOTHING AND FLUSH AFFECTED AREAS WITH WATER.

Respiratory Protection:USE OF RESPIRATORY PROTECTION DEPENDS ON VAPOR
CONCENTRATIONS ABOVE TIME-WEIGHTED TLV. USE NIOSH/MSHA APPROVED
CARTRIDGE RESPIRATOR OR GAS MASK.
Ventilation:GEN MECH VENT REC, MAY BE SUFFICIENT TO KEEP VAP CONC W/IN
TIME-WEIGHTED TLV RANGES. LOC EXHST:REQD IF GEN (SEE ING 4)
Protective Gloves:CHEMICAL RESISTANT PLASTIC OR RUBBER.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:IMPERMEABLE APRONS. EYE WASH AND SAFETY
SHOWERS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:SPREADING BURNING LIQUID W/WATER USED FOR COOLING
PURPOSES. MATLS TO AVOID:POTASSIUM-TERT BUTOXIDE. DIBUTYL PHTHALATE
CAN REACT W/OXIDIZING MATLS. VIOLENT REACTION W/CL*2. ETHYLENE GLY
COL CAN REACT VIOLENTLY W/CHLOROSULFONIC ACID, OLEUM, H*2SO*4 EFTS
OF OVEREXP:DAMAGE IN ANIMALS; BIRTH DEFECTS (ING 5)

HCC:N1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:15 @ 25C
Vapor Density:HVR/AIR
Spec Gravity:1.25-1.28
Evaporation Rate & Reference:< THAN ETHER
Solubility in Water:PARTIAL
Appearance and Odor:CHARACTERISTIC ODOR OF BUTYL ACETATE
Percent Volatiles by Volume:45.5

Stability Indicator/Materials to Avoid:YES
BUTYL ACETATE IS INCOMPATIBLE W/STRONG ALKALIES, ALSO CAN REACT
W/OXIDIZING MATLS. VIOLENT REACTION WITH (SUPP DATA)
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CO, CO*2. UNDER SEVERE THERMAL
DEGRADATION, LOW MOLECULAR WEIGHT HYDROCARBONS MAY BE FORMED.

Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH APPLICABLE
LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS.

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